Gold(0) Porphyrins on Gold Nanoparticles

Gold(0) porphyrins on gold nanoparticles.

Photoswitchable rotaxanes on gold nanoparticles.

We studied rotaxanes that consisted of a molecular axle, with a photoactive 9-Aryl-9-methoxy-acridane moiety at one end, and a tetracationic ring of cyclobis(paraquat-p-phenylene) (CBQT(4+)). The aim of the study was to deposit the axle ends onto gold nanoparticles (AuNPs). First, we introduced thioctic acid into the axle molecules. Then, rotaxanes were deposited on AuNPs by two methods: 1) Pse...

Gold Nanoparticles

Nanoparticles have become important materials in modern technologies compared with their bulk analogues not only as a result of their excellent structural features but also as a result of their unusual functional attributes. Most of the bulk materials we use in everyday life such as steel or sand are composed of micrometer scale particles. The properties of a material are related to the bonding...

Orientations of polyoxometalate anions on gold nanoparticles.

Cryogenic transmission electron microscopy of polyoxometalate-protected gold nanoparticles reveals that the Preyssler ion, [NaP(5)W(30)O(110)](14-), lies "face down" with its C(5) axis perpendicular to the gold surface, while the Finke-Droege ion, [P(4)W(30)Zn(4)(H(2)O)(2)O(112)](16-), is "tilted", with its long axis close to 60° from the normal to the surface.

On the coalescence of gold nanoparticles q

The present work investigates the coalescence process of two gold nanoparticles for a host of initial temperatures and starting radii in vacuum with the help of molecular dynamics (MD) simulations. Diverse mechanisms of the first sintering stage, characterized by a growing neck region, were found. The results are compared with a phenomenological macroscopic model based on an energy balance and ...